Fixierung von Sulfonsäure-hydraziden an dreikernigen Ruthenium-Clustern: Synthese und Struktur von (μ₂-H)Ru₃(CO)₉[μ₃-η²-H₂NNS(O)₂Mes] | Zendy

G. Rheinwald | Zendy; H. StoeckliEvans | Zendy; Georg SüßFink | Zendy

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Fixierung von Sulfonsäure-hydraziden an dreikernigen Ruthenium-Clustern: Synthese und Struktur von (μ₂-H)Ru₃(CO)₉[μ₃-η²-H₂NNS(O)₂Mes]

Author(s) -

G. Rheinwald,

H. StoeckliEvans,

Georg SüßFink

Publication year - 1993

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.1993.196

Subject(s) - ruthenium , chemistry , cleavage (geology) , bond cleavage , derivative (finance) , medicinal chemistry , crystallography , catalysis , materials science , organic chemistry , fracture (geology) , financial economics , economics , composite material

Sulfonic hydrazides were found to react thermally with Ru3(CO)12 without cleavage of the N–N bond resulting in the formation of trinuclear hydrazido clusters. The X-ray structure analysis of the derivative (μ2-H)Ru3(CO)9[μ3-η2-H2NNS(O)2Mes] shows a triangular Ru3 framework capped by an intact N–N unit.

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