Open AccessFixierung von Sulfonsäure-hydraziden an dreikernigen Ruthenium-Clustern: Synthese und Struktur von (μ₂-H)Ru₃(CO)₉[μ₃-η²-H₂NNS(O)₂Mes]
Author(s) -
Gerd Rheinwald,
Helen Stœckli-Evans,
Georg SüßFink
Publication year - 1993
Publication title -
chimia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.1993.196
Subject(s) - ruthenium , chemistry , cleavage (geology) , bond cleavage , derivative (finance) , medicinal chemistry , crystallography , catalysis , materials science , organic chemistry , fracture (geology) , financial economics , economics , composite material
Sulfonic hydrazides were found to react thermally with Ru3(CO)12 without cleavage of the N–N bond resulting in the formation of trinuclear hydrazido clusters. The X-ray structure analysis of the derivative (μ2-H)Ru3(CO)9[μ3-η2-H2NNS(O)2Mes] shows a triangular Ru3 framework capped by an intact N–N unit.