Chemo- and Regioselectivity in the Reaction of Tetrachloro- and Tetrabromophthalic Anhydrides and Imides with Thiolates | Zendy

W. Fischer | Zendy; Tammo Winkler | Zendy

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Chemo- and Regioselectivity in the Reaction of Tetrachloro- and Tetrabromophthalic Anhydrides and Imides with Thiolates

Author(s) -

W. Fischer,

Tammo Winkler

Publication year - 1991

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.1991.162

Subject(s) - vicinal , chemistry , regioselectivity , reagent , alkyl , aryl , halogen , reaction conditions , stoichiometry , organic chemistry , combinatorial chemistry , catalysis

The reaction of tetrachloro- and tetrabromophthalic anhydrides and -imides with in situ generated aryl and alkyl thiolates gives mono- to tetrathio-substituted derivatives depending on reagent, stoichiometry, and reaction conditions. The halogens non-vicinal to the carbonyl groups react regio- and chemoselectively under appropriate conditions. By this reaction, novel types of photosensitizers useful to photocross-link polymers are prepared.

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