Polycyclic Phosphiranes: Synthesis of C-Substituted BABAR-Phos Compounds | Zendy

Florian Läng | Zendy; Hansjörg Grützmacher | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Polycyclic Phosphiranes: Synthesis of C-Substituted BABAR-Phos Compounds

Author(s) -

Florian Läng,

Hansjörg Grützmacher

Publication year - 2003

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/000942903777679451

Subject(s) - phos , chemistry , catalysis , rhodium , ligand (biochemistry) , toluene , stereochemistry , organic chemistry , receptor , biochemistry

BABAR-Phos is a very stable polycyclic phosphirane which is easily synthesized in few steps from dibenzosuberenone. BABAR-Phos is remarkably stable and is not oxygenated with O2 nor does it react with sulfur in boiling toluene. BABAR-Phos can be used as a ligand in homogenous catalysis. Substituents at the carbon of the PC2 heterocycle can be introduced and asymmetric BABAR-Phos were prepared. The coordination chemistry of rhodium complexes containing these as ligands was investigated.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research