
Emulsifiers from renewable materials: an eco-friendly synthesis and properties
Author(s) -
Halina Szeląg,
Elwira Sadecka,
Roman Pawłowicz,
Agnieszka Kuziemska
Publication year - 2013
Publication title -
polish journal of chemical technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.279
H-Index - 20
eISSN - 1899-4741
pISSN - 1509-8117
DOI - 10.2478/pjct-2013-0035
Subject(s) - environmentally friendly , chemistry , emulsion , organic chemistry , fractionation , chemical engineering , ecology , engineering , biology
The focus of this study was the preparation of novel bio based polyglycerol emulsifiers characterized by a one pot synthesis, thus by modified properties with respect to interfacial activity and effectiveness as emulsion stabilizers. The final products of the esterification process, carried out in the presence of carboxylates were used directly as emulsifiers (without purification or fractionation). Polyglycerol emulsifiers obtained in proposed conditions can be tailored to stabilize the defined emulsion system. The modification of the surface activity of emulsifiers may be obtained by programming the fatty acid acyl group in the polyglycerol ester as well as the hydrocarbon chain length in sodium soap and concentration of this compound in the reaction mixture.