Open AccessSynthesis, Crystal structure, Vibrational, Optical and Dielectric properties Of 2-(2-Aminoethyl)-1-methylpyrrolidinum chloride hexachlorobismuthate (III) monohydrate [C7H18N2]2ClBiCl6.H2O
Author(s) -
Fayçal Ben Tahar,
Chakib Hrizi,
Slaheddine Chaabouni,
N. Chniba-Boudjada,
Nicolas Ratel Ramond,
Sergejus Balčiūnas,
M. V. Ivanov,
R. Mackevičiūtė,
J. Banys,
Radhouéne Chtourou
Publication year - 2013
Publication title -
journal of advances in chemistry
Language(s) - English
Resource type - Journals
ISSN - 2321-807X
DOI - 10.24297/jac.v9i3.1008
Subject(s) - orthorhombic crystal system , crystal structure , crystallography , intermolecular force , chemistry , dielectric , molecule , hydrogen bond , crystal (programming language) , octahedron , infrared spectroscopy , single crystal , analytical chemistry (journal) , materials science , organic chemistry , optoelectronics , computer science , programming language
Synthesis, crystal structure, vibrational and dielectric properties of [C7H18N2]2ClBiCl6.H2O are reported. The compound crystallizes at room temperature in the orthorhombic system, space group P212121, with the following unit cell parameters : a = 7.5500(6) Å, b = 18.3780(2) Å, c = 19.8980(13) Å, V = 2760.9(4) Å3 and four molecules per unit cell. The structure has been solved by three-dimensional Patterson synthesis and refined by least-squares analysis (R1 = 0.0463, wR2 = 0.0764). The crystal structure of the title compound, [C7H18N2]2ClBiCl6.H2O consists of 2-(2-Aminoethyl)-1-methylpyrrolidinium cations, [BiCl6]3- anions, Cl- anions and free water molecules. The Bi(III) cation is coordinated by six Cl- anions in slightly distorsed octahedral geometry. In the crystal, extensive intermolecular N-H…Cl hydrogen bonds occur. The charge-transfer (CT) interactions between 2-(2-Aminoethyl)-1-methylpyrrolidinium cation and the anionic hosts have been revealed by structural analysis and UV-vis spectroscopy. The dielectric properties have been investigated at temperature range from 100 to 300 K at various frequencies (1 KHz – 1 MHz). The evolution of dielectric constant as a function of temperature and frequency of pellet has been investigated in order to determine some related parameters.