Open AccessDIRECT SYNTHESIS OF 1.4-CIS POLYBUTADIENE WITH APPLICATION OF HETEROGENIZED DITHIOSYSTEM.
Author(s) -
Gyulyara Bagirov,
S.R. Rafiyeva,
F.A. Nasirov,
G.N. Hasanova,
A. D. Kuliyev,
A.M. Tagiyeva,
Nazil Janibayov
Publication year - 2015
Publication title -
journal of advances in chemistry
Language(s) - English
Resource type - Journals
ISSN - 2321-807X
DOI - 10.24297/jac.v11i6.856
Subject(s) - polybutadiene , polymerization , catalysis , mordenite , chemistry , aluminium , polymer chemistry , organic chemistry , copolymer , polymer , zeolite
The problems of phosphorusulphurization of mordenite, preparation of metalcomplex dithiophosphates and results of their investigation as the heterogenized catalytic systems in combination with aluminum-organic compounds in the polymerization process of butadiene are considered. It has been established that Ni- and Co-containing dithiosystem are the high-active and high-selective catalysts of this pricess