z-logo
open-access-imgOpen Access
Controlling Factors of the Particle Size of Spherical Silica Synthesized by Wet and Dry Processes
Author(s) -
Keiji Saiki,
Toshihiro Ishikawa
Publication year - 2021
Publication title -
european journal of engineering and technology research
Language(s) - English
Resource type - Journals
ISSN - 2736-576X
DOI - 10.24018/ejeng.2021.6.7.2631
Subject(s) - calcination , silane , monomer , materials science , particle size , particle (ecology) , chemical engineering , alkoxy group , silicon , hydrophobic silica , condensation , polymer chemistry , organic chemistry , chemistry , composite material , polymer , catalysis , alkyl , metallurgy , oceanography , physics , engineering , thermodynamics , geology
We clarified the controlling factors of the particle size of the amorphous silica synthesized by wet and dry processes. In the wet process using methyl-trimethoxy-silane as a starting monomer, the obtained particle size can be easily controlled by changing the reaction time appropriately. However, to obtain larger particles, a relatively long time is needed. After the condensation reaction was conducted for 50h, the silica particles (D50: 3?m) were synthesized by calcination at 550oC in air. To synthesize larger silica particles, we used silica-seed particles (8?m) to obtain very large spherical silica particles (D50: 20?m). Thus, although the wet process needs a relatively long reaction time, it is very useful for synthesizing spherical silica particles with a wide range of particle size. In the dry process, we used methyl-trimethoxy-silane (MTMS), tetra-ethoxy-silane (TEOS), and octamethyl-cyclotetrasiloxane (OMCTSO) as the starting materials. In this process, the size of the silica particles was dominated by the molecular structure of the monomer, in particular, the number of silicon atoms contained in the monomer and the bulkiness of the substituent group. The largest silica particles were synthesized from OMCTSO, which contains the largest number of silicon atoms.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.
Having issues? You can contact us here