Open AccessPhotocatalytic degradation of carbamate insecticides: Effect of different parameters
Author(s) -
Anđelka Tomašević,
Dušan Ž. Mijin,
Аleksandar Marinković,
Ilija Cvijetić,
Slavica Gašić
Publication year - 2019
Publication title -
pesticidi i fitomedicina
Language(s) - English
Resource type - Journals
eISSN - 2406-1026
pISSN - 1820-3949
DOI - 10.2298/pif1904193t
Subject(s) - carbofuran , carbamate , photocatalysis , degradation (telecommunications) , high performance liquid chromatography , chromatography , catalysis , materials science , nuclear chemistry , photochemistry , environmental chemistry , pesticide , biology , chemistry , organic chemistry , agronomy , telecommunications , computer science
Photocatalytic degradation of a model compound of the carbamate insecticide carbofuran in water was studied using polychromatic light and ZnO and TiO2 catalysts. The influence of operational parameters, such as reaction time and initial carbofuran concentration, on photocatalytic degradation was studied. A pseudo-first-order kinetic model was established and an almost complete removal of 88.4 mg L-1 of carbofuran occurred within 2 h under optimized conditions. The reactions were examined by UV spectroscopy and high performance liquid chromatography (HPLC). In addition, the photocatalytic efficiencies of ZnO and TiO2 were compared under the same reaction conditions.