Open AccessPalladium on carbon in PEG-400/Cyclohexane: Recoverable and recyclable catalytic system for efficient decarbonylation of aldehydes
Author(s) -
Nataša Terzić Jovanović,
Vladimir Ajdačić
Publication year - 2022
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc220128024t
Subject(s) - decarbonylation , chemistry , cyclohexane , catalysis , organic chemistry , palladium , solvent
A simple methodology for the decarbonylation of aldehydes catalysed by commercially available palladium on carbon in a green two-solvent system is reported. Various aromatic, aliphatic and heteroaromatic aldehydes were transformed to the corresponding decarbonylated products in good yields. Pro-duct isolation from the reaction mixture is simple in practice, and the catalyst can be reused three times.