Open AccessInfluence of electrochemical conditions on the regio- and stereoselectivity of selenocyclization of alkenyl hydantoins
Author(s) -
M Biljana Smit,
Barbara Stanić,
G Ljubinka Joksovic,
P Darko Asanin,
Zoran Simić
Publication year - 2021
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc201022023s
Subject(s) - stereoselectivity , electrochemistry , chemistry , bicyclic molecule , tricyclic , regioselectivity , medicinal chemistry , organic chemistry , combinatorial chemistry , electrode , catalysis
5-Alkenyl hydantoins and alkenyl spirohydantoins are converted into bicyclic and tricyclic hydantoins, under indirect electrochemical conditions, generating the phenylselenyl cation in situ. The reactions proceeded in good to exelent yields. The influence of electrochemical conditions on regio- and diastereoselectivity of the selenocyclization reactions is investigated.