Open AccessPalladium(II) complexes with R2edda derived ligands: Part VI. O,O’-diisopropyl-(S,S)-ethylenediamine-N,N’-di-2-(4-methyl)pentanoate dihydrochloride dihydrate and its palladium(II) complex: Synthesis and characterization
Author(s) -
Bojana B. Zmejkovski,
Tibor J. Sabo,
N Goran Kaludjerovic
Publication year - 2013
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc130113021z
Subject(s) - palladium , ethylenediamine , chemistry , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis
A new R2edda-type ester, O,O’-diisopropyl-(S,S)-ethylenediamine-N,N’-di-2-(4-methyl)-pentanoate dihydrochloride dihydrate, [(S,S)-H2iPr2eddl]Cl2∙2H2O, 1, and its palladium(II) complex, dichlorido(O,O’-diisopropyl-(S,S)-ethylenediamine-N,N’-di-2-(4-methyl)pentanoate)palla-dium(II) hemihydrate, [PdCl2{(S,S)-iPr2eddl}]∙0.5H2O, 2, were synthesized and characterized by elemental analysis, IR and NMR spectroscopy. As expected the palladium(II) complex is found in two from three diastereoisomeric forms (R,R), (S,S) and (R,S)≡(S,R). [Projekat Ministarstva nauke Republike Srbije, br. 172035