Open AccessNickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere
Author(s) -
Josef Husárek,
Richard Pstorek,
Michal Maloň,
Zedenek Sindalar,
Marek Pavlíček
Publication year - 2004
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0412053h
Subject(s) - dithiocarbamate , nickel , chemistry , diamagnetism , spectroscopy , coordination complex , chromophore , elemental analysis , inorganic chemistry , infrared spectroscopy , conductivity , coordination sphere , crystallography , metal , photochemistry , organic chemistry , magnetic field , crystal structure , physics , quantum mechanics
A series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)](X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, thermal analysis magnetochemical and conductivity measurements. On the basis of the results of the physico-chemical study, all complexes are diamagnetic, non-electrolytes with a square-planar NiS2PX chromophore.