The crystal structure of 14-0x0-13,14-seco-5α-cholest-13(18)-en-3β-yl acetate and the assignment of the configuration of its acetoxy derivatives | Zendy

Mira S. Bjelaković | Zendy; Vladimir B. Pavlović | Zendy; Ljubinka Lorenc | Zendy; Bernard Tinant | Zendy; JeanPaul Declercq | Zendy

Open Access

The crystal structure of 14-0x0-13,14-seco-5α-cholest-13(18)-en-3β-yl acetate and the assignment of the configuration of its acetoxy derivatives

Author(s) -

Mira S. Bjelaković,

Vladimir B. Pavlović,

Ljubinka Lorenc,

Bernard Tinant,

JeanPaul Declercq

Publication year - 2000

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc0008541b

Subject(s) - chemistry , fragmentation (computing) , crystal structure , stereochemistry , medicinal chemistry , oxidative phosphorylation , crystallography , biochemistry , computer science , operating system

The crystal structure of 14-oxo-13,14-seco-5?-cholest-13(18)-en-3?-yl acetate (2), obtained (in addition to the (E)-?l2-isomer 3) by oxidative fragmentation of the C(13)-C(14) bond of 14?-hydroxy-5?-cholestan-3?-yl acetate (1), was determined by X-ray analysis. In addition, the configurations of the acetoxy derivatives 4-6, formed by the thermal lead tetraacetate oxidation of 1, were deduced from the relevant 1?-NMR parameters.

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