Open AccessAntimony recovery from recycled terminals of lead-acid batteries with Na2CO3 and SiC after firstly SsB2O3 formation
Author(s) -
J.C. Jiménez-Lugos,
R.G. Sánchez-Alvarado,
Alejandro CruzRamírez,
J. A. RomeroSerrano,
Aurelio Hernández-Ramírez,
Jorge E. RiveraSalinas
Publication year - 2022
Publication title -
journal of mining and metallurgy. section b, metallurgy/journal of mining and metallurgy. section b, metallurgy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.42
H-Index - 20
eISSN - 2217-7175
pISSN - 1450-5339
DOI - 10.2298/jmmb210616052j
Subject(s) - antimony , antimony trioxide , antimony oxide , slag (welding) , materials science , metallurgy , metal , silicon , oxide , nuclear chemistry , chemistry , fire retardant
Terminals obtained from spent lead-acid batteries in Mexico contain around 2 wt% Sb. The terminals were melted in an electric furnace and then oxygen was injected at 750 ?C with a gas flow rate of 2 L/min to produce high purity Sb2O3. The antimony trioxide obtained was treated with a mixture of Na2CO3-SiC at 1000 ?C to obtain metallic antimony. The antimony trioxide was reduced by C present in reagents while silicon and sodium formed a slag phase. The amounts of Sb2O3 and SiC were held constant while the Na2CO3 was evaluated in the range from 30 to 42 wt%. The produced antimony and slag were characterized by the X-ray diffraction and SEM-EDS techniques. The addition of 34 wt% Na2CO3 led to the recovery of antimony up to 90.16 wt% (99.57 wt% purity) and the lowest antimony losses in the slag (2 wt%). In addition, the compounds Na2SiO3 and Na2Si2O5 formed in the slag indicated a more stable slag. Na2CO3 contents higher than 38 wt% decreased the antimony recovery since Na2Sb4O7 compound was promoted in the slag. The oxidation and reduction process was modeled in FactSage 7.3 software for a better understanding of the Na2CO3 and SiC additions on the antimony recovery rates and compounds formed in the slag.