Open AccessStudy of solid state interactions in the systems ZnFe2O4 - CaO, ZnFe2O4 - MgO and zinc cake with CaO and MgO
Author(s) -
Alexander Peltekov,
B. Boyanov
Publication year - 2013
Publication title -
journal of mining and metallurgy. section b, metallurgy/journal of mining and metallurgy. section b, metallurgy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.42
H-Index - 20
eISSN - 2217-7175
pISSN - 1450-5339
DOI - 10.2298/jmmb130624037p
Subject(s) - zinc ferrite , zinc , hydrometallurgy , solubility , chemistry , sulfuric acid , nuclear chemistry , inorganic chemistry , solid state , mössbauer spectroscopy , ferrite (magnet) , metallurgy , materials science , chemical engineering , engineering , composite material , crystallography
The solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and Mössbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850-1200ºC and duration up to 180 min. It has been established that Ca2+ and Mg2+ ions exchange Zn2+ in ferrite partially and the solubility of zinc in a 7% sulfuric acid solution increases. The possibilities for utilization of the obtained results in zinc hydrometallurgy have been discussed