Open AccessRelationship between cooling rate and microsegregation in bottom-chilled directionally solidified ductile irons
Author(s) -
Wen Shiung Chang,
Chun-Ming Lin
Publication year - 2013
Publication title -
journal of mining and metallurgy. section b, metallurgy/journal of mining and metallurgy. section b, metallurgy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.42
H-Index - 20
eISSN - 2217-7175
pISSN - 1450-5339
DOI - 10.2298/jmmb120702034c
Subject(s) - materials science , electron microprobe , microstructure , metallurgy , casting , mold , cooling curve , copper , thermocouple , directional solidification , dendrite (mathematics) , graphite , heat transfer , continuous casting , composite material , thermodynamics , geometry , mathematics , physics
This study explores the relationship between cooling rate and microsegregation of directionally solidified ductile iron. The unidirectional heat transfer system used in this research is made up of a copper mold kept chilled by circulating water and embedded in the bottom of Furan sand mold. Thermocouples are connected to the computer measuring system to record the cooling curves of the castings at a distance of 0, 30, 60 and 90 mm from the chilled copper mold surface. Alloys including Mn, Cr, Cu, Ni and Ti were added to the specimens. Electron microprobe analysis (EPMA) was employed to examine distribution of elements between the dendrite arms and nodular graphite. Results show that unidirectional heat transfer affects directly the solidification mode and microstructure of the casting. The cooling curves reveal that local solidification time increases with increasing distance from the chilled copper mold surface. Different solidification rates with corresponding microstructure and element segregation were observed in the same unidirectionally solidified casting. Local solidification time was closely related to element segregation. The effective segregation coefficient (Keff) calculated using the Scheil equation was found to vary, according to the stage of solidification. The actual segregation characteristics of complex alloys generally follow the Scheil equation