Open Access
CATALYST PROCESSING AND RECYCLING
Author(s) -
Jakub Kovalčík,
Martin Straka,
Peter Kačmáry,
Tomáš Pavlík
Publication year - 2021
Publication title -
acta tecnología
Language(s) - English
Resource type - Journals
ISSN - 2453-675X
DOI - 10.22306/atec.v7i3.118
Subject(s) - rhodium , catalysis , precious metal , palladium , platinum , materials science , platinum group , metallurgy , noble metal , automotive industry , ceramic , waste management , metal , chemistry , engineering , aerospace engineering , biochemistry
Discussed auto catalysts contain interesting quantities of platinum noble metals, palladium and rhodium according to the type of auto catalyst, thereby becoming a possible source of these metal aims to acquaint themselves with catalysts in general, their history and last but not least the possibilities of processing and obtaining noble metals for further use. The article deals with knowledge at the theoretical level of use of methods in processing depleted catalysts. It is pyrometallurgical and hydrometallurgical methods. The platinum group metals (PGMs) palladium, platinum, and rhodium represent the key materials for automotive exhaust gas treatment. Since there are currently no adequate alternatives, the importance of these metals for the automotive industry is steadily rising. The high value of PGMs in spent catalysts justifies their recycling. The state-of the-art technology is to melt the ceramic carrier and collect the precious fraction in a liquid metal bath. As the feed material has quite high melting points, huge amounts of energy are required for this process. Hydrometallurgical treatments of the spent catalysts offer the possibility to recycle the PGMs with less energy and time demands. Moreover, automotive catalysts contain further valuable materials to improve the exhaust gas treatment. These compounds, like cerium oxide, cannot be recovered in pyrometallurgical processes.