SYNTHESIS OF SAFRYL KETONE FROM SAFROLE | Zendy

Hanoch Julianus Sohilait | Zendy; Hardjono Sastrohamidjojo | Zendy; Sabirin Matsjeh | Zendy; J. Stuart Grossert | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

SYNTHESIS OF SAFRYL KETONE FROM SAFROLE

Author(s) -

Hanoch Julianus Sohilait,

Hardjono Sastrohamidjojo,

Sabirin Matsjeh,

J. Stuart Grossert

Publication year - 2010

Publication title -

indonesian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.273

H-Index - 14

eISSN - 2460-1578

pISSN - 1411-9420

DOI - 10.22146/ijc.21874

Subject(s) - safrole , chemistry , ketone , alcohol , fourier transform infrared spectroscopy , proton nmr , allyl alcohol , organic chemistry , nuclear magnetic resonance spectroscopy , proton magnetic resonance , catalysis , nuclear magnetic resonance , chromatography , physics , quantum mechanics

Synthesis of safryl ketone from safrole has been achieved through conversion of allyl group to secondary alcohol, followed by oxidation with PCC-Al2O3. The oxymecuration-demercuration reaction of safrole with HgSO4-NaBH4 yields safryl alcohol (66.38%) and the oxidation of safryl alcohol with PCC-Al2O3 yields safryl ketone (62.92%). The structure elucidation of these products was conducted using Fourier Transformed Infra Red Spectroscopy (FTIR), Proton-Nuclear Magnetic Resonance (1H-NMR) and Mass Spectroscopy (MS). Keywords: safryl ketone, safrole

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research