Open AccessЭлектрохимический контроль электронной проводимости тонких пленок металлоорганических полимеров
Author(s) -
М.П. Карушев,
А.М. Тимонов
Publication year - 2021
Publication title -
pisʹma v žurnal tehničeskoj fiziki
Language(s) - English
Resource type - Journals
eISSN - 1726-7471
pISSN - 0320-0116
DOI - 10.21883/pjtf.2021.16.51329.18830
Subject(s) - electrochemistry , polymer , conductivity , materials science , doping , monomer , electrical resistivity and conductivity , conductance , conductive polymer , nickel , chemical engineering , polymer chemistry , inorganic chemistry , electrode , chemistry , composite material , metallurgy , optoelectronics , electrical engineering , engineering , mathematics , combinatorics
The dependence of the conductivity in thin films of polymer complexes of nickel with N4 ligands with macrocyclic and chelate structure on the doping level has been studied by the electrochemical in-situ conductance method. The electrochemical conductivity window of polymers depends on the structure of the monomers and approached 1.2 V for the macrocyclic complex. Electrochemical doping changes the electrical resistance of the investigated materials by 4 orders of magnitude