Open AccessСпектральное исследование фотодинамических процессов в системе C-=SUB=-60-=/SUB=--(н-метилпирролидон)-кислород
Author(s) -
I. M. Kislyakov,
И. М. Белоусова,
Валерий Михайлович Киселев,
И. В. Багров,
Андрей Михайлович Стародубцев,
Tianju Zhang,
Jun Wang
Publication year - 2021
Publication title -
optika i spektroskopiâ
Language(s) - English
Resource type - Journals
eISSN - 2782-6694
pISSN - 0030-4034
DOI - 10.21883/os.2021.12.51736.2429-21
Subject(s) - intersystem crossing , phosphorescence , singlet oxygen , triplet state , photoexcitation , quantum yield , singlet state , ultrafast laser spectroscopy , quenching (fluorescence) , absorption spectroscopy , singlet fission , photochemistry , picosecond , absorption (acoustics) , materials science , chemistry , nanoclusters , analytical chemistry (journal) , atomic physics , oxygen , spectroscopy , molecule , excited state , laser , fluorescence , optics , nanotechnology , physics , organic chemistry , chromatography , composite material , quantum mechanics
The processes of photoexcitation and energy transfer in an air-saturated solution of fullerene C60 in n-methylpyrrolidone are studied. With femtosecond laser pumping at a wavelength л(p) = 520 nm, transient absorption spectra were obtained in the range 470-750 nm. Broadband absorption is observed at л > 650 nm as a result of aggregation of fullerene molecules, characterized by a short decay time of the picosecond scale. The analysis of the time dependencies indicates the presence of several processes. Within the proposed interpretation, we state a remarkable reduction in the time of singlet-triplet intersystem crossing with an increase of nanocluster size while the rapid quenching of the singlet state varies only slightly. The quantum yield of the triplet state can therefore increase, reaching 0.14. The phosphorescence spectra of singlet oxygen with a maximum at л = 1276 nm were measured with LED excitation at various wavelengths in the range 370-625 nm. The lifetime and quenching rate constant of singlet oxygen in n-methylpyrrolidone are determined. The combined quantum yield of triplet fullerene and singlet oxygen in n-methylpyrrolidone is estimated as 0.74. The efficiency spectra of the singlet oxygen photosensibilization in the C60-(n-methylpyrrolidone)-oxygen system are obtained, indicating the increasing role of large nanoclusters in this process during aging of the solution.