Спектрально-люминесцентные свойства разнолигандных комплексных соединений европия(III) c o-метоксибензойной кислотой и фосфорсодержащими нейтральными лигандами | Zendy

И.В. Калиновская | Zendy

Open Access

Спектрально-люминесцентные свойства разнолигандных комплексных соединений европия(III) c o-метоксибензойной кислотой и фосфорсодержащими нейтральными лигандами

Author(s) -

И.В. Калиновская

Publication year - 2020

Publication title -

журнал технической физики

Language(s) - English

Resource type - Journals

eISSN - 1726-748X

pISSN - 0044-4642

DOI - 10.21883/os.2020.06.49397.352-19

Subject(s) - europium , triphenylphosphine oxide , luminescence , chemistry , ligand (biochemistry) , oxide , inorganic chemistry , ion , triphenylphosphine , photochemistry , crystallography , materials science , organic chemistry , biochemistry , receptor , optoelectronics , catalysis

The spectral and luminescent properties of complex compounds of europium (III) with o-methoxybenzoic acid and island-containing phosphorus-containing neutral ligands of the composition Eu (MOBA) 3 • 3Н2О and Eu (MOBA) 3 • L, where MOBA is o-methoxybenzoic acid, D is studied (hexamethylphosphoric triamide), tppo (triphenylphosphine oxide), Et6pa (hexaethylphosphotriamide). It was found that the excitation energy is transferred to the europium ion both from the levels of o-methoxybenzoic acid and from the levels of phosphorus-containing neutral ligands.The electronic absorption spectra, the luminescence excitation spectra, and the Stark structure of 5D0-7Fj (j = 0-2) electronic transitions in the luminescence spectra of mixed-ligand complex europium (III) complex o-methoxybenzoates are analyzed. Europium (III) methoxybenzoate with triphenylphosphine oxide has the highest luminescence intensity.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research