Open AccessТеплоемкость скандобората NdSc-=SUB=-3-=/SUB=-(BO_3)-=SUB=-4-=/SUB=-
Author(s) -
Е.В. Еремин,
Н.Д. Андрюшин,
И.А. Гудим,
М.С. Павловский,
В.Р. Титова
Publication year - 2021
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2021.12.51688.188
Subject(s) - trigonal crystal system , neodymium , bismuth , condensed matter physics , debye , atmospheric temperature range , ab initio , debye model , ab initio quantum chemistry methods , heat capacity , lattice (music) , chemistry , materials science , thermodynamics , crystallography , physics , crystal structure , optics , metallurgy , laser , organic chemistry , molecule , acoustics
Single crystals of trigonal neodymium scandoborate NdSc3(BO3)4 were grown by the group method from a solution-melt based on bismuth trimolybdate. The molar heat capacity C(T) was studied in the temperature range 2-300 K and magnetic fields up to 9 T. The experimental curve was approximated by the combined Debye-Einstein model. The lattice contribution was determined from ab-initio calculations. Schottky anomaly was observed in the low-temperature region C(T) with the applied magnetic field.