Open AccessЛюминесцентные свойства в видимом и коротковолновом ИК-спектральных диапазонах апатитов Sr-=SUB=-2-=/SUB=-La-=SUB=-8-x-=/SUB=-Tm-=SUB=-x-=/SUB=-(GeO-=SUB=-4-=/SUB=-)-=SUB=-6-=/SUB=-O-=SUB=-2-=/SUB=- (x= 0.1-1.0)
Author(s) -
И. В. Бакланова,
О. А. Липина,
Л. Л. Сурат,
А.Ю. Чуфаров,
А.П. Тютюнник,
В. Г. Зубков
Publication year - 2020
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2020.08.49610.045
Subject(s) - germanate , luminescence , phosphor , materials science , infrared , ultraviolet , analytical chemistry (journal) , thermal stability , ion , apatite , optics , chemistry , mineralogy , optoelectronics , doping , physics , organic chemistry , chromatography
The Sr2La8-xTmx(GeO4)6O2 (x = 0.1–1.0) solid solutions with the apatite structure were synthesized by the solid-state method for the first time, the spectral-luminescence properties were studied and the prospects of these compounds as phosphors of the visible and short-wave infrared ranges were demonstrated. The luminescence of germanates Sr2La8-xTmx(GeO4)6O2 under ultraviolet excitation is characterized by high blue color purity and color coordinates close to commercially available phosphors. In addition, it was shown that Sr2La8-xTmx(GeO4)6O2 compounds efficiently convert 808 nm laser radiation into a series of emission lines in the spectral range of 1.3–2.2 µm due to successive 3H4 → 3F4 and 3F4 →3H6 transitions in Tm3+ ions. The Sr2La7.6Tm0.4(GeO4)6O2 germanate with a maximum emission intensity in the short-wave infrared region demonstrates high thermal stability of luminescence in the range of 30–220 °С.