Open AccessДипольное упорядочение и ионная проводимость в NASICON-подобных структурах типа Na-=SUB=-3-=/SUB=-Sc-=SUB=-2-=/SUB=-(PO_4)-=SUB=-3-=/SUB=-
Author(s) -
А.С. Ногай,
А. А. Ногай,
С.Ю. Стефанович,
Ж.М. Солиходжа,
Д.Е. Ускенбаев
Publication year - 2019
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2019.11.48401.395
Subject(s) - ionic conductivity , dipole , fast ion conductor , ionic bonding , crystallography , crystal structure , conductivity , trigonal crystal system , materials science , polarization (electrochemistry) , phase (matter) , electrical resistivity and conductivity , chemistry , ion , physics , electrolyte , electrode , organic chemistry , quantum mechanics
Problems of the dipole ordering and ionic conductivity of Na_3Sc_2(PO_4)_3 polycrystal that has three polymorphic phases—α, β, and γ—are studied. The features of the α-Na_3Sc_2(PO_4)_3 crystal structure and the dipole ordering and relaxation polarization in the α and β phases are specified. The origin of the dipole ordering in the α phase and the partial dipole disordering in the β-Na_3Sc_2(PO_4)_3, as well as the high ionic conductivity in the β and γ phases of the Na_3Sc_2(PO_4)_3 polycrystal are associated with phase transformations α → β, β → γ that result in structural changes of the rhombohedral {[Sc_2(PO_4)_3]^3–}_3∞ crystalline framework. A model explaining the emergence of the dipole ordering and the ionic conductivity phenomena in Na_3Sc_2(PO_4) is proposed.