Open AccessПроводимость композитных пленок на основе проводящего полимера PEDOT : PSS, оксида графена и наночастиц TiO-=SUB=-2-=/SUB=- для контактных слоев перовскитных фотовольтаических структур
Author(s) -
A. A. Bazanova,
V. N. Petrov,
А. Н. Алешин
Publication year - 2019
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2019.04.47429.334
Subject(s) - pedot:pss , materials science , perovskite (structure) , activation energy , chemical engineering , electrical resistivity and conductivity , oxide , titanium dioxide , nanotechnology , polymer , composite material , chemistry , metallurgy , electrical engineering , engineering
The electrical properties of composite films based on conductive polymer PEDOT: PSS, graphene oxide (GO), and titanium dioxide nanoparticles (TiO_2) (PEDOT: PSS– TiO_2 and GO–TiO_2) used as contact layers of organic and perovskite photovoltaic structures have been studied. As a result of the study of morphology by atomic force microscopy, it was found that the PEDOT: PSS–TiO_2 and GO–TiO_2 films have a globular structure with a grain size of ~200–300 nm. The current–voltage characteristics of the PEDOT: PSS–TiO_2 and GO–TiO_2 films are measured in the temperature range of 80–300 K, the dependences of the resistivity versus temperature, ρ( T ), which have an activation character, are obtained. It is established that as the temperature decreases, the ρ( T ) dependences show a transition from large values of the activation energy (570 meV and 329 meV) to lower values (25 meV and 2.2 meV) for the PEDOT: PSS–TiO_2 and GO–TiO_2 films, respectively. The mechanisms of transport of charge carriers in the materials studied are discussed.