Open AccessЭлектрическая поляризация в ErCrO-=SUB=-3-=/SUB=-, индуцированная локальными полярными областями
Author(s) -
В.А. Санина,
Б.Х. Ханнанов,
Е.И. Головенчиц,
М.П. Щеглов
Publication year - 2019
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2019.03.47242.286
Subject(s) - polar , ferroelectricity , polarization (electrochemistry) , ion , materials science , crystallization , condensed matter physics , impurity , electric field , crystallography , polarization density , magnetic field , dielectric , chemistry , magnetization , physics , optoelectronics , organic chemistry , quantum mechanics , astronomy
Electric polarization in ErCrO_3 single crystals has been investigated in the temperature range of 5‒370 K. Ferroelectric ordering has not been found in any of the directions. However, electric polarization induced by restricted polar domains of structural origin has been observed. These domains are formed in the crystal matrix near impurity Bi^3+ ions partially substituting Er^3+ ions during the growth of single crystals by the method of spontaneous crystallization using solvent Bi_2O_3. The restricted polar domains form the superparaelectric state. Hysteresis loops with remanent polarization, both along the c axis and in the [110] directions, have been observed below some temperatures T _fr (in the frozen superparaelectric state). The polarization exists up to certain temperatures, which depend on the applied electric field orientation with respect to the crystal axes and exceed significantly temperature T _N of magnetic ordering. These temperatures correspond to the condition kT _fr ≈ E _A for activation barriers at the boundaries of the restricted polar domains.