Open AccessВлияние дейтерирования на фазовые переходы в диоксотетрафториде ванадия
Author(s) -
Е.В. Богданов,
Е.И. Погорельцев,
М.В. Горев,
М.С. Молокеев,
И.Н. Флеров
Publication year - 2019
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2019.02.47134.230
Subject(s) - phase diagram , tetrahedron , thermodynamics , materials science , dielectric , thermal stability , phase transition , crystal (programming language) , entropy (arrow of time) , crystallography , phase (matter) , ammonia , chemistry , physics , organic chemistry , optoelectronics , computer science , programming language
The crystals of (ND_4)_3VO_2F_4 with a high degree of deuteration (~87%) have been grown and a significant (~1.5%) increase in the unit cell volume has been detected. The decrease in the chemical pressure leads to a change in the sequence of phase transitions due to wedging-out of one of the rhombic phases observed in (NH_4)_3VO_2F_4. The thermal physical studies have been carried out and the entropies, deformations, and pressure coefficients related to structural transformations have been determined. The T – p phase diagram has been built and the pressure and temperature boundaries of crystal phase stability have been determined. The dielectric studies demonstrate a nonferroelectric nature of the phase transitions in (ND_4)_3VO_2F_4. The experimental and model entropies are compared. Based on the decrease in the entropy as a result of deuteration, a hypothesis on significant but not limited anharmonism of vibrations of ammonia tetrahedral corresponding to the disordering is proposed.