Open AccessФазовый переход металл-диэлектрик в тонких пленках диоксида ванадия, легированного железом
Author(s) -
В.Н. Андреев,
В.А. Климов
Publication year - 2018
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2018.12.46734.142
Subject(s) - electrical resistivity and conductivity , atmospheric temperature range , materials science , doping , metal–insulator transition , condensed matter physics , crystallite , conductivity , insulator (electricity) , thermal conductivity , metal , phase transition , phase (matter) , analytical chemistry (journal) , thermodynamics , chemistry , physics , metallurgy , composite material , organic chemistry , chromatography , quantum mechanics
The electrical conductivity of polycrystalline V_(1 – _ x )Fe_ x O_2 films has been investigated in a wide temperature range, which covers both the metal and insulator phase regions. It is shown that with an increase in the iron concentration the metal–insulator phase transition shifts toward lower temperatures, while the temperature range of the transition in doped samples additionally broadens as compared with pure VO_2. To explain the temperature dependence of the electrical conductivity of the V_(1 – _ x )Fe_ x O_2 insulator phase, a hopping conductivity model has been used, which takes into account the effect of thermal vibrations of atoms on the resonance integral. The values of parameter ε have been calculated as a function of the degree of VO_2 doping.