Open AccessВлияние кобальта на кристаллическую структуру и магнетизм электрон-допированного оксида Sr-=SUB=-0.8-=/SUB=-Ce-=SUB=-0.2-=/SUB=-MnO-=SUB=-3-=/SUB=-
Author(s) -
Г. В. Базуев,
Т. И. Чупахина,
А. В. Королев
Publication year - 2018
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2018.12.46729.195
Subject(s) - antiferromagnetism , tetragonal crystal system , ferromagnetism , perovskite (structure) , materials science , condensed matter physics , spin glass , crystal structure , crystallography , transition temperature , paramagnetism , chemistry , physics , superconductivity
The Sr_0.8Ce_0.2Mn_1 – _ y Co_ y O_3 – δ ( y = 0.2, 0.3, 0.4, 0.5, and 0.6) complex oxides with the perovskite structure obtained from simple oxides by the solid–state reaction technique have been examined using structural analysis and magnetic measurements. Substitution of Co for Mn in the dilute Sr_0.8Ce_0.2MnO_3 antiferromagnet with a Néel temperature of T _N = 210 K leads to a decrease in the degree of tetragonal distortion of the crystal structure and transition to the cubic cell. The degeneracy of the antiferromagnetic interaction ( T _N = 138 K at y = 0.2) observed at the first stage of the substitution of Co for Mn changes for its gradual enhancement with an increase in the magnetic transformation temperature up to 239 K at y = 0.6. An increase in the Co content weakens the competition between the ferromagnetic and antiferromagnetic couplings and reduces the temperature of the transition to the spin-glass-like state. The magnetic inhomogeneity and formation of Co^2+–Mn^4+ ferromagnetic clusters in Sr_0.8Ce_0.2Mn_0.4Co_0.6O_2.69 at 140 K have been observed.