Особенности спектров ядерного магнитного резонанса полигидроксилированного фуллерена C-=SUB=-60-=/SUB=-(OH)-=SUB=-n-=/SUB=- | Zendy

А.C. Мазур | Zendy; А.Е. Карпунин | Zendy; О.В. Проскурина | Zendy; В.И. Герасимов | Zendy; И.В. Плешаков | Zendy; В.В. Матвеев | Zendy; Ю.И. Кузьмин | Zendy

Open Access

Особенности спектров ядерного магнитного резонанса полигидроксилированного фуллерена C-=SUB=-60-=/SUB=-(OH)-=SUB=-n-=/SUB=-

Author(s) -

А.C. Мазур,

А.Е. Карпунин,

О.В. Проскурина,

В.И. Герасимов,

И.В. Плешаков,

В.В. Матвеев,

Ю.И. Кузьмин

Publication year - 2018

Publication title -

физика твердого тела

Language(s) - English

Resource type - Journals

eISSN - 1726-7498

pISSN - 0367-3294

DOI - 10.21883/ftt.2018.07.46138.018

Subject(s) - fullerene , benzene , aqueous solution , molecule , chemistry , catalysis , solid state , carbon 13 nmr , mixing (physics) , materials science , organic chemistry , physics , quantum mechanics

Polyhydroxylated fullerene C_60(OH)_ n (with an estimated number of hydroxyl groups n = 38–44) synthesized from pure fullerene by mixing a benzene solution of C_60 with a NaOH aqueous solution in the presence of a catalyst was studied with ^1H and ^13C solid-state nuclear magnetic resonance. Possible features of the structure of a molecule shell were revealed from ^1H NMR data. The ^13C spectrum showed a peak splitting with an increase in temperature, which is probably due to fullerenol isomers.

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