Open AccessОсобенности спектров ядерного магнитного резонанса полигидроксилированного фуллерена C-=SUB=-60-=/SUB=-(OH)-=SUB=-n-=/SUB=-
Author(s) -
А.C. Мазур,
А.Е. Карпунин,
О.В. Проскурина,
В.И. Герасимов,
И.В. Плешаков,
В.В. Матвеев,
Ю.И. Кузьмин
Publication year - 2018
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2018.07.46138.018
Subject(s) - fullerene , benzene , aqueous solution , molecule , chemistry , catalysis , solid state , carbon 13 nmr , mixing (physics) , materials science , organic chemistry , physics , quantum mechanics
Polyhydroxylated fullerene C_60(OH)_ n (with an estimated number of hydroxyl groups n = 38–44) synthesized from pure fullerene by mixing a benzene solution of C_60 with a NaOH aqueous solution in the presence of a catalyst was studied with ^1H and ^13C solid-state nuclear magnetic resonance. Possible features of the structure of a molecule shell were revealed from ^1H NMR data. The ^13C spectrum showed a peak splitting with an increase in temperature, which is probably due to fullerenol isomers.