Open AccessОсобенности структуры и диэлектрических свойств керамик на основе титаната натрия-висмута
Author(s) -
Е. Д. Политова,
Н. В. Голубко,
Г. М. Калева,
А. В. Мосунов,
Н.В. Садовская,
Д.А. Белькова,
С.Ю. Стефанович
Publication year - 2018
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2018.03.45538.04d
Subject(s) - materials science , dielectric , ceramic , permittivity , stoichiometry , phase transition , phase (matter) , analytical chemistry (journal) , ferroelectricity , conductivity , dielectric permittivity , relative permittivity , electrical resistivity and conductivity , mineralogy , thermodynamics , composite material , chemistry , optoelectronics , chromatography , organic chemistry , physics , electrical engineering , engineering
The phase formation, specific features, and the dielectric properties of the ceramics of compositions from the region of morphotropic interface in the (Na_0.5Bi_0.5)TiO_3–BaTiO_3 system modified by Bi(Mg_0.5Ti_0.5)O_3 and also low-melting additions KCl, NaCl–LiF, CuO, and MnO_2 that favor the control of the stoichiometry and the properties of the ceramics have been studied. The ceramics are characterized by ferroelectric phase transitions that are observed as jumps at temperatures near 400 K and maxima at T _m ~ 600 K in the temperature dependences of the dielectric permittivity. The phase transitions at ~400 K demonstrate the relaxor behavior indicating the existence of polar domains in the nonpolar matrix. An increase in the content of Bi(Mg_0.5Ti_0.5)O_3 favor a decrease in the electrical conductivity and dielectric losses of the samples, and the relative dielectric permittivity at room temperature ε_rt is retained quite high, achieving the highest values ε_rt = 1080–1350 in the ceramics modified with KCl.