Open AccessНовый люминофор ИК-диапазона на основе германата Sr-=SUB=-3-=/SUB=-La-=SUB=-2-=/SUB=-(Ge-=SUB=-3-=/SUB=-O-=SUB=-9-=/SUB=-)-=SUB=-2-=/SUB=- : Nd-=SUP=-3+-=/SUP=-, Ho-=SUP=-3+-=/SUP=-
Author(s) -
М. А. Мелкозерова,
И. В. Бакланова,
О. А. Липина,
А.Ю. Чуфаров,
А.П. Тютюнник,
В. Г. Зубков
Publication year - 2018
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2018.02.45393.206
Subject(s) - luminescence , isostructural , holmium , neodymium , phosphor , analytical chemistry (journal) , materials science , ion , silicate , emission spectrum , atomic physics , spectral line , chemistry , laser , crystallography , crystal structure , optics , physics , optoelectronics , organic chemistry , chromatography , astronomy
Cyclogermanate Sr_3La_2(Ge_3O_9)_2, isostructural to silicate Sr_3Er_2(Si_3O_9)_2, activated by neodymium and holmium is obtained for the first time by the precursor method. Ion Nd^3+ in the structure of Sr_3La_2(Ge_3O_9)_2 is a sensitizer of the infrared luminescence of Ho^3+. Excitation by radiation with a wavelength of 808 nm leads to a series of emission lines in the luminescence spectra of Sr_3La_2- x Nd_ x (Ge_3O_9)_2 : Ho^3+ in the short-wave and middle-IR ranges (1.0–3.4 μm). The highest intensity of lines at 2.1 and 2.7 μm, associated with the ^5 I _7 → ^5 I _8 and ^5 I _6 → ^5 I _7 transitions in the Ho^3+ ion, is found for compositions containing traces of holmium. Based on the analysis of the concentration dependences of the luminescence intensity, an optimal composition of the phosphor is determined, which ensures the maximum efficiency of conversion of laser radiation energy. The data obtained are interpreted in the assumption of cross-relaxation energy transfer from Nd^3+ to Ho^3+.