Open AccessВлияние решеточного и спин-фононного вкладов на температурное поведение расщепления основного состояния Gd-=SUP=-3+-=/SUP=- в SrMoO-=SUB=-4-=/SUB=-
Author(s) -
А.Д. Горлов
Publication year - 2018
Publication title -
fizika tverdogo tela
Language(s) - English
Resource type - Journals
eISSN - 1726-7498
pISSN - 0367-3294
DOI - 10.21883/ftt.2018.02.45388.169
Subject(s) - impurity , electron paramagnetic resonance , atmospheric temperature range , lattice (music) , spectral line , condensed matter physics , physics , phonon , hamiltonian (control theory) , ground state , chemistry , atomic physics , nuclear magnetic resonance , thermodynamics , mathematical optimization , mathematics , quantum mechanics , astronomy , acoustics
The temperature behavior of the EPR spectra of the Gd^3+ impurity center in single crystals of SrMoO_4 in the temperature range T = 99–375 K is studied. The analysis of the temperature dependences of the spin Hamiltonian b _2 ^0 ( T ) = b _2( F ) + b _2( L ) and P _2 ^0 ( T ) = P _2( F ) + P _2( L ) (for Gd^157) describing the EPR spectrum and contributing to the Gd^3+ ground state splitting Δ E is carried out. In terms of the Newman model, the values of b _2( L ) and P _2( L ) depending on the thermal expansion of the static lattice are estimated; the b _2( F ) and P _2( F ) spin-phonon contributions determined by the lattice ion oscillations are separated. The analysis of b _2 ^0 ( T ) and P _2 ^0 ( T ) is evidence of the positive contribution of the spin-phonon interaction; the model of the local oscillations of the impurity cluster with close frequencies ω describes well the temperature behavior of b _2( F ) and P _2( F ).