Open AccessСуперионная проводимость твердых растворов (TlGaSe-=SUB=-2-=/SUB=-)-=SUB=-1-x-=/SUB=-(TlInS-=SUB=-2-=/SUB=-)-=SUB=-x-=/SUB=-
Author(s) -
R. M. Sardarly,
А. П. Абдуллаев,
N. A. Alieva,
F. T. Salmanov,
М.Ю. Юсифов,
А.А. Оруджева
Publication year - 2018
Publication title -
fizika i tehnika poluprovodnikov
Language(s) - English
Resource type - Journals
eISSN - 1726-7315
pISSN - 0015-3222
DOI - 10.21883/ftp.2018.10.46448.8749
Subject(s) - solid solution , conductivity , electrical resistivity and conductivity , analytical chemistry (journal) , dielectric spectroscopy , phase diagram , relaxation (psychology) , anomaly (physics) , materials science , phase (matter) , electrical impedance , chemistry , condensed matter physics , physics , electrode , psychology , social psychology , organic chemistry , chromatography , quantum mechanics , metallurgy , electrochemistry
amples of (TlGaSe_2)_1 – _ x (TlInS_2)_ x solid solutions are synthesized. The frequency dependences (2 × 10^1–10^6 Hz) of components of the total complex impedance are studied by the impedance spectroscopy technique and relaxation processes are investigated depending on the composition of the (TlGaSe_2)_1 – _ x (TlInS_2)_ x solid solution in the solubility region ( x = 0–0.4). Corresponding diagrams on the ( Z ''– Z ') complex plane are analyzed using the equivalent substitutional circuit method. An anomaly in the temperature dependence of the electrical conductivity, which manifests itself in an abrupt increase in the conductivity, is found for the studied (TlGaSe_2)_1 – _ x (TlInS_2)_ x solid solution at 400 K. This peculiarity is associated with the phase transition into the superionic state.