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Titanium Dioxide‐Mediated Photocatalytic Degradation of Humic Acid under Natural Sunlight
Author(s) -
He Yi
Publication year - 2013
Publication title -
water environment research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 73
eISSN - 1554-7531
pISSN - 1061-4303
DOI - 10.2175/106143012x13378023685790
Subject(s) - humic acid , photocatalysis , chemistry , titanium dioxide , adsorption , mineralization (soil science) , dissolved organic carbon , degradation (telecommunications) , catalysis , organic matter , nuclear chemistry , environmental chemistry , inorganic chemistry , chemical engineering , organic chemistry , telecommunications , fertilizer , computer science , nitrogen , engineering
In this article, photocatalytic degradation of humic acid, a predominant type of natural organic matter present in ground and surface waters, was conducted using a commercial titanium dioxide catalyst under natural sunlight irradiation in a batch photoreactor. Various parameters, such as photocatalyst loading, pH value, irradiation intensity, initial concentration, and illumination time, had a significant influence on humic acid removal. The adsorption isotherm of TiO 2 dosage fit to Langmuir's isotherm equation well, and the reaction kinetics of initial dissolved organic carbon (DOC) concentration increased with the increase of TiO 2 dosage but decreased with the increase of initial DOC. The mineralization of humic acid revealed that the large molecular weight organics with aromatic and hydrophobic properties were removed, while the most persistent components were the shortest UV‐absorbing and hydrophilic low‐molecular‐weight compounds. This study indicates that the solar/TiO 2 photocatalytic degradation is a promising process for humic acid removal from water.