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Complete Dechlorination of Endosulfan and Lindane Using Mg 0 /Pd +4 Bimetallic System
Author(s) -
Aginhotri Prakhar,
Mahidrakar Amit B.,
Gautam Sumit Kumar
Publication year - 2011
Publication title -
water environment research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 73
eISSN - 1554-7531
pISSN - 1061-4303
DOI - 10.2175/106143011x12928814445096
Subject(s) - lindane , chemistry , bimetallic strip , endosulfan , radiochemistry , environmental chemistry , pesticide , catalysis , organic chemistry , biology , agronomy
A Mg 0 /Pd +4 bimetallic system was evaluated to dechlorinate endosulfan and lindane in the aqueous phase. Studies were conducted with endosulfan and lindane separately, with or without acid in a 1:1 (v/v) water:acetone phase. In the absence of any acid, higher degradation of endosulfan and lindane was observed using Mg 0 /Pd +4 doses of 10/0.5 and 4/0.1 mg/mL, respectively. Acetone plays an important role in facilitating the dechlorination reaction by increasing the solubilities of pesticides. Dechlorination kinetics for endosulfan and lindane (30 and 50 mg/L [30 and 50 ppm] concentration of each pesticide) were conducted with varying Mg 0 /Pd +4 doses, and the time‐course profiles were well‐fitted into exponential curves. The optimum observed rate constants ( k obs ') for endosulfan and lindane were obtained with Mg 0 /Pd +4 doses of 5/0.5 and 4/0.1 mg/mL, respectively. Gas chromatography‐mass spectrometry analyses revealed that endosulfan and lindane were dechlorinated completely into their hydrocarbon skeletons—Bicyclo [2,2,1] hepta 2‐5 diene and benzene, respectively.