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Full‐Scale Removal of Arsenate and Chromate from Water Using a Limestone and Ochreous Sludge Mixture as a Low‐Cost Sorbent Material
Author(s) -
Cederkvist Karin,
Holm Peter E.,
Jensen Marina B.
Publication year - 2010
Publication title -
water environment research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 73
eISSN - 1554-7531
pISSN - 1061-4303
DOI - 10.2175/106143009x12487095237314
Subject(s) - sorbent , arsenate , chromate conversion coating , water treatment , waste management , chemistry , environmental science , environmental chemistry , arsenic , mineralogy , environmental engineering , metallurgy , adsorption , materials science , chromium , engineering , organic chemistry
The oxyanions arsenate (AsO 4 3− ) and chromate (CrO 4 2− ) are major freshwater contaminants. Arsenate is a problematic contaminant in drinking water reservoirs, and chromate limits the use of urban stormwater runoff. High‐capacity, low‐cost, energy‐efficient treatment technologies are required for the removal of these toxic anions from freshwater sources. Using a 50‐m‐long dual porosity filter, with limestone as filtering grains, treating stormwater runoff from Copenhagen, Denmark, we tested if addition of the waste product ochreous sludge can improve the removal of arsenate (As) and chromate (Cr) without compromising the calcite's removal affinity towards metallic cations. Upon on‐site embedding of the ochreous sludge, removal of arsenic and chromium was improved greatly, and copper (Cu) removal remained high. Steady‐state effluent concentrations were reduced from 31 to 2 µg As/L, 127 to 1.5 µg Cr/L, and 18 to 9.6 µg Cu/L upon mixing with the ochreous sludge. Limestone‐ochreous sludge represents a promising low‐cost oxyanion and cation sorbent operating at neutral pH without pH control.