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Anion and Cation Leaching or Desorption from Activated Carbons from Municipal Sludge and Poultry Manure as Affected by pH
Author(s) -
Fitzmorris Kari B.,
Lima Isabel M.,
Marshall Wayne E.,
Reimers Robert S.
Publication year - 2006
Publication title -
water environment research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 73
eISSN - 1554-7531
pISSN - 1061-4303
DOI - 10.2175/106143006x95375
Subject(s) - chemistry , leaching (pedology) , sorption , zinc , activated carbon , cadmium , environmental chemistry , desorption , copper , chromium , inorganic chemistry , nuclear chemistry , adsorption , environmental science , organic chemistry , soil water , soil science
The conversion of municipal sludge and poultry manure to activated carbon results in a significant ash fraction that contains several different anions and cations. The objectives of this study were to determine whether the select ions are released or leached from virgin carbon into the sorption medium at different pH values. Activated carbon was placed in solutions of pH 1, 5, or 7, and the leaching of six cations (cadmium, chromium, copper, nickel, lead, and zinc) and two anions (arsenate and selenate) was recorded. Considerable quantities of zinc and copper were removed at pH 1 from all carbon sources. However, the amounts leached at pH 5 and 7 were small or undetectable. Our results indicate that leaching or desorption from carbons made from municipal sludge or poultry manure is pH‐dependent and occurs readily under highly acidic conditions but minimally under pH conditions typically seen in contaminated water or wastewater.