Intramolecular energy- and electron-transfer reactions in polymetallic complexes. Annual report | Zendy

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Intramolecular energy- and electron-transfer reactions in polymetallic complexes. Annual report

Author(s) -

Joe Peterson

Publication year - 1991

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/34192

Subject(s) - intramolecular force , pyrazine , chemistry , electron transfer , electron , charge (physics) , crystallography , medicinal chemistry , photochemistry , stereochemistry , physics , nuclear physics , quantum mechanics

The complexes (tpy)Ru(II)(tpp)Co(III)(PPhEt{sub 2})H{sub 2}{sup 3+}, (NC){sub 3}Fe(II)(tpp)Co(III)(PPhEt{sub 2})H{sub 2} and (NC){sub 3}Fe(II)(tpp)Co(III)(PPh{sub 3})H{sub 2} (where tpp = 2,3,5,6-tetrakis(2{prime}-pyridyl)pyrazine), were prepared and their photochemistry studied. Reasons for the low quantum yields for H{sub 2} production are discussed briefly. A series of FeRuRh complexes is being prepared. Plans for the coming year on intramolecular energy transfer and charge separation are discussed

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