Tank characterization report for single-shell tank 241-T-102

A major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-T-102. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-T-102 waste; and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendixes. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order milestone M-44-05. Characterization information presented in this report originated from sample analyses and known historical sources. The most recent core sampling of tank 241-T-102 (March 1993) predated the existence of data quality objectives (DQOs). An assessment of the technical issues from the currently applicable DQOs was made using data from the 1993 push mode core sampling event, a July 1994 grab sampling event, and a May 1996 vapor flammability measurement. Historical information for tank 241-T-102, provided in Appendix A, includes surveillance information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a process knowledge model. Appendix B contains further sampling and analysis data from the March 1993 push mode core sampling event and data from the grab sampling event in August 1994 and May 1996 vapor flammability measurement. Of the two push mode cores taken in March of 1993, cores 55 and 56, only core 55 had sufficient recovery for analysis. Therefore, only the results from the analysis of core 55 can be used to partially satisfy the requirements of the safety DQO. The sampling and analysis of the 1994 grab samples were performed in accordance with Schreiber (1994) and the results were originally reported in WHC (1994). Appendix C provides information on the statistical analysis and numerical manipulation of data used in issue resolution. Appendix D contains the evaluation to establish the best basis for the inventory estimate and the statistical analysis performed for this evaluation. Appendix E is the bibliography that resulted from an in-depth literature search of all known information sources applicable to tank 241-T-102 and its respective waste type. The reports listed in Appendix E may be found in the Tank Characterization and Safety Resource Center