Open AccessSynthesis, Characterization and Properties of MgB2 Doped Polyaniline
Author(s) -
Shumaila ,
M. Zulfequar,
M. Husain
Publication year - 2017
Publication title -
journal of modern materials
Language(s) - English
Resource type - Journals
ISSN - 2456-4834
DOI - 10.21467/jmm.4.1.1-9
Subject(s) - polyaniline , doping , materials science , fourier transform infrared spectroscopy , polymerization , conductivity , band gap , conductive polymer , analytical chemistry (journal) , thermal stability , infrared , polymer , chemical engineering , composite material , chemistry , optoelectronics , optics , organic chemistry , physics , engineering
Present paper reports novel synthesis of MgB2 doped Polyaniline (PAni). PAni is synthesized through oxidative polymerization method using Ammonium Peroxodisulphate and doped by different compositions of MgB2. The DC conductivity of undoped and doped polymers is measured in the temperature range of 300 – 400 K and is found to increase with temperature. An increase in conductivity by five orders of magnitude has been observed after doping. Conduction mechanism was also studied in all of the samples. FT-IR (Fourier Transform Infrared spectroscopy) and ultraviolet (UV)-Visible studies confirm the occurrence of PAni in conducting emeraldine salt form in the composites. The optical studies signify that absorption mechanism is due to direct allowed transition and the band gap decrease after doping. Thermal stability of all the composites has been explained on the basis of variation in Tc–Tg and ∆Hc by using DSC (Differential Scanning Calorimetery) measurements.