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Urea Decreases Nitrous Oxide Emissions Compared with Anhydrous Ammonia in a Minnesota Corn Cropping System
Author(s) -
Venterea Rodney T.,
Dolan Michael S.,
Ochsner Tyson E.
Publication year - 2010
Publication title -
soil science society of america journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.836
H-Index - 168
eISSN - 1435-0661
pISSN - 0361-5995
DOI - 10.2136/sssaj2009.0078
Subject(s) - anhydrous , fertilizer , urea , agronomy , chemistry , greenhouse gas , cropping system , nitrous oxide , agroecosystem , ammonia , crop rotation , soil water , crop residue , nitrogen , zoology , environmental science , crop , agriculture , biology , ecology , organic chemistry , soil science
Quantifying N 2 O emissions from corn ( Zea mays L.) and soybean [ Glycine max (L.) Merr.] fields under different fertilizer regimes is essential to developing national inventories of greenhouse gas emissions. The objective of this study was to compare N 2 O emissions in plots managed for more than 15 yr under continuous corn (C/C) vs. a corn–soybean (C/S) rotation that were fertilized during the corn phase with either anhydrous NH 3 (AA) or urea (U). During three growing seasons, N 2 O emissions from corn following corn were nearly identical to corn following soybean. In both systems, however, N 2 O emissions with AA were twice the emissions with U. After accounting for N 2 O emissions during the soybean phase, it was estimated that a shift from C/S to C/C would result in an increase in annual emissions of 0.78 kg N ha −1 (equivalent to 0.11 Mg CO 2 –C ha −1 ) when AA was used, compared with only 0.21 kg N ha −1 (0.03 Mg CO 2 –C ha −1 ) with U. In light of trends toward increased use of U, these results suggest that fertilizer‐induced soil N 2 O emissions may decline in the future, at least per unit of applied N, although further study is needed in different soils and cropping systems. While soil CO 2 emissions were 20% higher under C/C, crop residue from the prior year did not affect soil inorganic N or dissolved organic C during the subsequent season. We also compared different flux‐calculation schemes, including a new method for correcting chamber‐induced errors, and found that selection of a calculation method altered N 2 O emissions estimates by as much as 35%.

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