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Quartz Oxygen Isotopic Stability in Relation to Isolation from Sediments and Diversity of Source
Author(s) -
Sridhar K.,
Jackson M. L.,
Clayton R. N.
Publication year - 1975
Publication title -
soil science society of america journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.836
H-Index - 168
eISSN - 1435-0661
pISSN - 0361-5995
DOI - 10.2136/sssaj1975.03615995003900060046x
Subject(s) - quartz , dissolution , mineralogy , amorphous solid , boric acid , oxygen , scanning electron microscope , geology , chemistry , materials science , metallurgy , crystallography , composite material , organic chemistry
The NaOH boiling treatment to remove amorphous silica relics in the quartz isolation procedure is unnecessary because the subsequent H 2 SiF 6 treatment dissolves both the amorphous silica relics and feldspars. Washing with 0.1 N HF, water, and saturated boric acid in the new procedure removed fluorates that precipitate during the H 2 SiF 6 treatment. Failure to remove the fluorates depressed the oxygen yield (to as much as 85%) of theoretical SiO 2 and slightly raised the quartz weight percent, but the oxygen isotopic ratio of quartz derived from various sources was not affected by these washings, by Na 2 S 2 O 7 fusion, or by H 2 SiF 6 treatment. When 35 to 45% of the outer shells of the 1–3.5, 3.5–7, and 7–10 µm quartz size fractions from Cretaceous (Pierre) marine shales was dissolved with 3 N HF, the quartz δ 18 O decreased by 0.8, 2.1, and 2.6 o/oo for a central‐basin shale and 0.7, 1.2, and 0.8 o/oo for a near‐shore shale, respectively. The trend, the greater the particle size the greater the δ 18 O decrease, is the opposite of that expected (finer particles, higher specific surface) if the δ 18 O decrease by HF treatment is a result of dissolving an isotopically exchanged portion and/or overgrowths in outer shells. The decrease appeared by scanning electron microscopy (SEM) to result from preferential dissolution of the cements holding fine quartz crystals (formed at low temperature) together as silt‐size clusters. A systematic increase in δ 18 O with decreasing grain size occurred in the quartz from the near‐shore shale (> 10 µm quartz, 16.1 o/oo; < 1 µm quartz, 21.8 o/oo). The increase was 6.7 o/oo from the central‐basin shale (> 10 µm quartz, 18.8 o/oo; < 1 µm quartz, 25.5 o/oo). The wide variation appears, from quartz particle morphology (SEM) and the response to partial dissolution, to result mainly from a mixing within each size fraction of different proportions of individually homogeneous quartz grains formed at various temperatures. Because of quartz oxygen isotopic stability, the isotopic ratio can be reliably used to trace source or provenance of fluvial and eolian sediments and soil parent materials.