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Chemical Conversion of Parathion on Soil Surfaces
Author(s) -
Yaron Bruno
Publication year - 1975
Publication title -
soil science society of america journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.836
H-Index - 168
eISSN - 1435-0661
pISSN - 0361-5995
DOI - 10.2136/sssaj1975.03615995003900040021x
Subject(s) - parathion , soil water , chemistry , organic matter , montmorillonite , kaolinite , adsorption , hydrolysis , decomposition , environmental chemistry , phosphate , clay minerals , mineralogy , organic chemistry , pesticide , soil science , agronomy , geology , biology
Chemical conversion of parathion was studied on a range of sterile soils widely different in organic matter content and clay mineralogy. After 130 days' incubation at room temperature, conversion ranged between 3–23% for air‐dried samples and was < 10% for moist ones in all the soils studied. The conversion was found to proceed via hydrolysis of the phosphate ester bond. A conversion mechanism is proposed. The conversion was affected by soil constituents like clay and organic matter—the rate decreasing in the order:—kaolinite > montmorillonite > organic matter, this being inversely related to the adsorption affinity of these materials for parathion. This phenomenon is explained by assuming that surface catalysis of parathion occurs at specific active sites only. For almost all the soils studied, the presence of water apparently blocked the active sites required for parathion decomposition, indicating that the soils' catalytic activity is moisture dependent.