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Gypsum Amendment Reduces Redox‐Induced Phosphorous Release from Freshly Manured, Flooded Soils to Floodwater
Author(s) -
Dharmakeerthi Randombage S.,
Kumaragamage Darshani,
Indraratne Srimathie P.,
Goltz Doug
Publication year - 2019
Publication title -
journal of environmental quality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.888
H-Index - 171
eISSN - 1537-2537
pISSN - 0047-2425
DOI - 10.2134/jeq2018.08.0308
Subject(s) - amendment , gypsum , soil water , chemistry , manure , redox , surface runoff , environmental chemistry , pore water pressure , environmental science , agronomy , soil science , ecology , geology , geotechnical engineering , biology , inorganic chemistry , political science , law , paleontology
The effectiveness of gypsum in reducing runoff P losses from soils and the mechanisms responsible are well documented; however, gypsum amendment effects in reducing redox‐induced P losses from flooded soils are less researched and documented. We examined the effect of gypsum amendment on P release from freshly manured soils to pore water and floodwater with continuous flooding for 56 d in the laboratory. Three soils (Pembina, Denham, and Dencross series) collected from Manitoba, Canada, were preincubated with liquid swine manure. Each preincubated manured soil was packed into vessels with or without recycled wallboard gypsum in triplicates and flooded for 56 d, during which pore water and floodwater were sampled weekly and analyzed for pH and dissolved reactive P (DRP), Ca, Mg, Fe, and Mn concentrations. Change in soil redox potential (Eh) with flooding was also monitored. Wallboard gypsum amendment significantly decreased the pore water and surface floodwater DRP concentrations in all three soils for most days after flooding (DAF). The Dencross soil, which had Olsen P about fivefold greater than the other soils, showed the greatest magnitude decrease in DRP concentration with gypsum amendment, by 1.27 mg L −1 on 49 DAF and 0.99 mg L −1 on 21 DAF for pore water and floodwater, respectively. Gypsum amendment (i) delayed the Eh reduction with flooding beyond +200 mV, (ii) decreased pore water pH, and (iii) increased concentrations of Ca, Mg, and Mn in pore water favoring precipitation of P, all of which may have directly or indirectly reduced the P release from flooded soils to overlying floodwater. Core Ideas Floodwater P concentration increased with flooding time in all soils and treatments. Redox‐induced P release was less from gypsum‐amended than unamended soils. Gypsum amendment reduced both pore water and floodwater P concentrations. Adding gypsum reduced floodwater P concentration to a maximum of 57%. The effectiveness of gypsum in reducing P release from flooded soils is soil dependent.