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Temporal and Spatial Patterns of Nitrate in a Claypan Soil
Author(s) -
Ghidey F.,
Alberts E. E.
Publication year - 1999
Publication title -
journal of environmental quality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.888
H-Index - 171
eISSN - 1537-2537
pISSN - 0047-2425
DOI - 10.2134/jeq1999.00472425002800020024x
Subject(s) - surface runoff , nitrate , environmental science , fertilizer , soil horizon , hydrology (agriculture) , groundwater , surface water , spatial variability , soil water , soil test , soil science , agronomy , geology , chemistry , ecology , environmental engineering , statistics , geotechnical engineering , mathematics , organic chemistry , biology
The temporal and spatial patterns of NO 3 ‐N were studied on a 35‐ha field located in the claypan soil region of north‐central Missouri. Soil samples were collected from the 0‐ to 5‐, 5‐ to 10‐, and 10‐ to 15‐cm depths and were analyzed for NO 3 ‐N concentrations. Surface water samples from the field were collected for NO 3 ‐N and NH 4 ‐N analysis during each surface runoff event. Groundwater samples were also taken from the field wells four times a year for 5 yr and analyzed for NO 3 ‐N concentrations. The effects of topography, depth to claypan, soil pH, organic matter (OM) content, cation exchange capacity (CEC), and soil water content on the spatial distribution of NO 3 ‐N concentration were also evaluated. Nitrate‐N concentration in the 0‐ to 5‐cm soil depth increased in the first few weeks following application, then decreased rapidly and was very low at harvest. During the study period, nitrate movement below the layer of fertilizer application was very low, and <5% of the total N applied in the soil was lost to surface runoff. Nitrate‐N concentration in groundwater samples decreased by an average of 0.40 mg L −1 yr −1 from 1992 to 1996. The semivariograms did not exhibit strong spatial dependency except for the samples collected 1 and 4 wk after fertilizer applications in 1993 and 1995, respectively. Nitrate‐N concentration was poorly correlated to soil water content and depth to claypan and relatively strongly correlated to elevation and soil pH.