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Charge Properties and Nitrate Adsorption of Some Acid Southeastern Soils
Author(s) -
Eick Matthew J.,
Brady Warren D.,
Lynch Colleen K.
Publication year - 1999
Publication title -
journal of environmental quality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.888
H-Index - 171
eISSN - 1537-2537
pISSN - 0047-2425
DOI - 10.2134/jeq1999.00472425002800010016x
Subject(s) - adsorption , chemistry , soil water , nitrate , chloride , cation exchange capacity , groundwater , saturation (graph theory) , point of zero charge , surface charge , leaching (pedology) , sulfate , environmental chemistry , inorganic chemistry , soil science , geology , geotechnical engineering , mathematics , organic chemistry , combinatorics
Numerous studies have been conducted examining nitrate (NO 3 ) leaching losses from agricultural land. Simulation models have been developed that allow one to predict the potential of NO 3 to leach to groundwater. However, many of these models treat NO 3 as a conservative tracer and do not evaluate surface chemistry. This study evaluated the surface charge properties and NO 3 adsorption capacity of four acid southeastern subsoils. Significant anion exchange capacity and NO 3 retention was found for two of the soils. Point of zero net charge (PZNC) was determined using an ion exchange method. Values of 3.1 and 3.6 were determined for two of the soils while PZNC values were not quantifiable for the other two soils in the pH range of 3 to 7. Nitrate adsorption isotherms were measured on untreated and chloride‐saturated soils. Nitrate adsorption maxima determined from the linearized form of the Langmuir equation ranged from 1.40 to 2.13 cmol c kg −1 . Coefficients of determination ( R 2 ) and adsorption maxima increased after chloride saturation. This was attributed to competition from anions such as sulfate, fluoride, and phosphate. Net positive charge and NO 3 retention were found to depend on the type and quantity of both variable and permanent charged minerals present in the soil and the composition of the exchange complex. These results demonstrated that acid subsoils high in variable charge minerals may have the potential to retard NO 3 movement to groundwater. Therefore, simulation models may need to account for NO 3 adsorption when modeling NO 3 movement in acid soils dominated by variable charge minerals.