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The Use of Zonal Centrifugation in Delineating Trace Element Distributions in Sewage Sludges from the Dayton, Ohio, Area
Author(s) -
Bergman Steven C.,
Ritter Charles J.,
Zamierowski Edward E.,
Cothern C. Richard
Publication year - 1979
Publication title -
journal of environmental quality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.888
H-Index - 171
eISSN - 1537-2537
pISSN - 0047-2425
DOI - 10.2134/jeq1979.00472425000800030030x
Subject(s) - trace element , chemistry , environmental chemistry , sewage , atomic absorption spectroscopy , sewage sludge , trace (psycholinguistics) , mineralogy , environmental science , environmental engineering , organic chemistry , linguistics , philosophy , physics , quantum mechanics
Density gradient zonal cenfrifugation, using tetrabromoethane‐ethanol solutions as density gradients, was used to fractionate two sewage sludges. The distributions of Cd, Cu, Pb, Ni, and Zn in the sludge fractions were determined using atomic absorption spectrophotometry. Trace element concentrations are related to density in a simple pattern. Seventy‐five weight percent of the total trace elements in the sludges are contained in low‐density (1.60 to Z.10 g/cm 3 ), organic‐rich fractions. A small portion of the total trace elements in sludge is also associated with minerals such as sulfides and sulfates in high‐density fractions. Because organic‐rich fractions of sludge contain the highest absolute amount of trace elements, it is concluded that most of the trace elements are located in organic compounds in the sludges studied. Furthermore, it is suggested that particular organic compounds, within a limited density range, contain the greatest concentrations of trace elements.