Open AccessStudy of Molecular Interactions of Water- Soluble Polymer at Several Temperatures in Solution
Author(s) -
Jawad Kadhim Abaies
Publication year - 2009
Publication title -
mağallaẗ baġdād li-l-ʿulūm
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.167
H-Index - 6
eISSN - 2411-7986
pISSN - 2078-8665
DOI - 10.21123/bsj.6.4.757-762
Subject(s) - excimer , monomer , polymer , fluorescence , methanol , solvent , solvation , methacrylic acid , hydrogen bond , copolymer , molecule , materials science , atmospheric temperature range , chemistry , emission spectrum , analytical chemistry (journal) , photochemistry , spectral line , thermodynamics , organic chemistry , physics , quantum mechanics , astronomy
Molecular interactions between 2-isopropenylnaphthalene-methacrylic acid (IPNMA) block copolymer( as a model for water- soluble polymer) and methanol at several temperatures were studied using fluorescence techniques , Fluorescence spectrum for (IPNMA) exhibits two emission bands at around 342 nm and 387 nm corresponding to the monomer and the excimer bands , respectively .The fluorescence spectra of dilute solution of (IPNMA) in methanol were recorded in temperature range of 8- 45?C . Plot of the excimer to monomer intensity ratio Ie/Im versus temperature was obtained, which shows double lines with positive slopes crossing at 25?C , the increasing of slope value above this temperature is small which indicates that there is stronger solvation of methanol molecules to polymer coil at temperature below 25? C arising from hydrogen bond formation between the polymer and the solvent .