Open AccessPreparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds
Author(s) -
Baghdad Science Journal
Publication year - 2017
Publication title -
mağallaẗ baġdād li-l-ʿulūm
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.167
H-Index - 6
eISSN - 2411-7986
pISSN - 2078-8665
DOI - 10.21123/bsj.14.3.575-581
Subject(s) - acetophenone , chemistry , molar conductivity , nuclear chemistry , aqueous solution , sulfamethoxazole , melting point , octahedral molecular geometry , magnetic susceptibility , metal ions in aqueous solution , metal , octahedron , atomic absorption spectroscopy , conductivity , inorganic chemistry , ion , medicinal chemistry , crystallography , organic chemistry , catalysis , biochemistry , physics , quantum mechanics , antibiotics
Acetophenone sulfamethoxazole and 3-Nitrobenzophenone sulfamethoxazole were prepared from the reaction of sulfamethoxazole with two ketones. The prepared ligands were identified by (C.H.N) analysis and UV-VIS, FT-IR spectroscopic techniques. Metal complexes of the two ligands were prepared in an aqueous alcohol with Zn (II), Mn (II) and Cu (II) ions with a molar ratio1:1. The proposed general formula for the resulting complexes was [ML.CL2.H2O]H2O .The complexes were characterized by (C.H.N) technique , spectroscopic methods ,conductivity, atomic absorption ,magnetic susceptibility measurements and melting point. According to the results obtained, the suggested geometry is to be octahedral for all the complexes.